界面聚合制备含杯芳烃结构的交联膜The preparation of cross-linked membrane containing calix[4]arene through interfacial polymerization
张力婉,刘冬青,张丹丹,尹宇航,赵新雨
摘要(Abstract)：
通过界面聚合将对叔丁基-杯[4]芳烃四-O-乙酰氯的正己烷溶液分别与己二胺、辛二胺及双端氨基聚乙二醇1000水溶液进行界面缩聚,制备出3种杯芳烃为交联点的无支撑聚合物薄膜,通过IR和SEM等手段对3种薄膜的化学结构和形貌进行了表征.结果表明,杯芳烃与双端氨基聚乙二醇1000形成的交联膜平滑、致密、具有黏性,适合在支撑膜表面形成含杯芳烃结构的聚酰胺皮层,可用于制备复合膜.
关键词(KeyWords)： 界面聚合法;交联;杯[4]芳烃膜;双端胺聚乙二醇;烷基二胺
基金项目(Foundation): 国家863基金项目(2012AA03A602)
作者(Author): 张力婉,刘冬青,张丹丹,尹宇航,赵新雨
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